{"id":25755,"date":"2021-12-19T10:21:57","date_gmt":"2021-12-19T02:21:57","guid":{"rendered":"https:\/\/www.paiqinano.com\/?p=25755"},"modified":"2021-12-18T10:57:59","modified_gmt":"2021-12-18T02:57:59","slug":"li-air%e7%94%b5%e6%b1%a0-acs-chao-li%ef%bc%9a%e5%85%b7%e6%9c%89%e8%b6%85%e7%96%8f%e6%b0%b4%e9%94%82%e4%bf%9d%e6%8a%a4%e5%b1%82%e7%9a%84%e9%94%82%e7%a9%ba%e6%b0%94%e7%94%b5%e6%b1%a0","status":"publish","type":"post","link":"https:\/\/www.paiqinano.com\/?p=25755","title":{"rendered":"Li-Air\u7535\u6c60\/ACS\/ Chao Li\uff1a\u5177\u6709\u8d85\u758f\u6c34\u9502\u4fdd\u62a4\u5c42\u7684\u9502\u7a7a\u6c14\u7535\u6c60"},"content":{"rendered":"<p><img decoding=\"async\" src=\"\/wp-content\/uploads\/2021\/12\/20211215142154-61b9fa029ba85.jpg\" title=\"1.jpg\" alt=\"1.jpg\" \/><\/p>\n<p><br style=\"margin: 0px;padding: 0px;max-width: 100%\" \/><\/p>\n<p><strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u3010\u6bd5\u4e1a\u8bba\u6587\u8fde\u63a5\u3011<\/p>\n<p>https:\/\/dx.doi.org\/10.1021\/acsami.0c05494<\/p>\n<p><strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u3010\u521b\u4f5c\u8005\u4f01\u4e1a\u3011<\/p>\n<p>Fudan University<\/p>\n<p><br style=\"margin: 0px;padding: 0px;max-width: 100%\" \/><\/p>\n<p><strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u3010\u8bba\u6587\u6458\u8981\u3011<\/p>\n<p><strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u6587\u4e2d\u62a5\u5bfc\u4e86\u5177\u5907\u8d85\u758f\u6c34\u6027\u7684\u51dd\u80f6\u5242\u884d\u5316\u7684\u5206\u5c42\u6b21\u591a\u5b54\u7ed3\u6784\u78b3(HDHPC)\u5c42\u88ab\u8bc1\u5b9e\u662f\u9502\u7a7a\u6c14\u7535\u6c60\u7684\u5408\u7406\u9502\u9632\u62a4\u5c42\uff0c\u5176\u53ef\u4ee5\u6291\u6b62\u5faa\u73af\u7cfb\u7edf\u6d41\u7a0b\u4e2d\u7684\u6c34\u8fdb\u653b\u548c\u9502\u679d\u6676\u7684\u4ea7\u751f\u3002\u56e0\u800c\uff0c\u6839\u636eHDHPC\u9632\u62a4\u5c42\u7684\u9502\u7a7a\u6c14\u7535\u6c60\u5728\u5468\u8fb9\u7a7a\u6c14\u4e2d\u4e3b\u8981\u8868\u73b0\u51fa\u660e\u663e\u7684\u5faa\u73af\u7cfb\u7edf\u53ef\u9760\u6027(40%\u7684\u7a7a\u6c14\u6e7f\u5ea6\u4e0b)\uff0c\u8fd9\u8fdc\u597d\u4e8e\u6c92\u6709HDHPC\u9632\u62a4\u5c42\u7684\u9502\u7a7a\u6c14\u7535\u6c60\u3002\u79d1\u5b66\u7814\u7a76\u8fd8\u8868\u660e\uff0c\u9502\u7a7a\u6c14\u7535\u6c60\u4e2dO<sub style=\"margin: 0px;padding: 0px;max-width: 100%\">2<\/sub>\/Li<sub style=\"margin: 0px;padding: 0px;max-width: 100%\">2<\/sub>O<sub style=\"margin: 0px;padding: 0px;max-width: 100%\">2<\/sub>\u7684\u8f6c\u6362\u5c06\u4e0d\u5229\u526f\u4ea7\u54c1\u548c\u7535\u89e3\u8d28\u6eb6\u6db2\u7684\u6eb6\u89e3\u3002HDHPC\u9632\u62a4\u5c42\u7684\u5e94\u7528\u5f00\u62d3\u4e86\u5728\u73af\u5883\u8d28\u91cf\u4e2d\u5f00\u53d1\u8bbe\u8ba1\u6027\u80fd\u5353\u8d8a\u9502\u7a7a\u6c14\u7535\u6c60\u7684\u6709\u6548\u9014\u5f84\u3002<\/p>\n<p><strong style=\"margin: 0px;padding: 0px;max-width: 100%\"><br style=\"margin: 0px;padding: 0px;max-width: 100%\" \/><\/p>\n<p><strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u3010<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">TOC\u3011<\/p>\n<p style=\"text-align: center;line-height: 2em\"><strong style=\"margin: 0px;padding: 0px;max-width: 100%\"><img decoding=\"async\" src=\"\/wp-content\/uploads\/2021\/12\/20211215142154-61b9fa02ddd48.jpg\" title=\"2.jpg\" alt=\"2.jpg\" \/><\/p>\n<p>\u00a0<br style=\"margin: 0px;padding: 0px;max-width: 100%\" \/><\/p>\n<p><strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u3010\u5b9e\u9a8c\u65b9\u6cd5\u3011<\/p>\n<p><strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u751f\u6210<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">RU-CNTs<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u590d\u5408\u6750\u8d28<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">:<\/p>\n<p><strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u5c06<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">116\u00a0<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">mgRuCl<sub style=\"margin: 0px;padding: 0px;max-width: 100%\">3\u00b7<\/sub>xH<sub style=\"margin: 0px;padding: 0px;max-width: 100%\">2<\/sub>O<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u878d\u89e3\u5728\u53bb\u79bb\u5b50\u6c34<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">(60\u00a0<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">ml<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">)<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u4e2d\uff0c\u968f\u540e\u5411\u9971\u548c\u6eb6\u6db2\u4e2d\u6dfb\u52a0<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">150 mg<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u7eb3\u7c73\u78b3\u7ba1<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">(CNTs),<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u62cc\u548c\u534a\u5c0f\u65f6\u540e\uff0c\u5c06\u83b7\u5f97\u7684\u9971\u548c\u6eb6\u6db2\u4f4e\u6e29\u5e72\u71e5\uff0c\u5728<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">250\u2103,5% H<sub style=\"margin: 0px;padding: 0px;max-width: 100%\">2<\/sub>\/Ar<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u6df7\u548c\u6c1b\u56f4\u4e2d\uff0c\u4ee5<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">5\u2103min<sup style=\"margin: 0px;padding: 0px;max-width: 100%\">-1<\/sup><strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u7684\u52a0\u70ed\u901f\u5ea6\u953b\u70e7<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">2<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u949f\u5934\u3002<\/p>\n<p><strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u51dd\u80f6\u5242\u7ea7\u591a\u5b54\u7ed3\u6784\u78b3<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">(HDHPC)<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u9632\u62a4\u5c42\u7684\u5236\u53d6<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">:<\/p>\n<p><strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u00a0 \u00a0 \u00a0 \u00a0\u2460\u00a0\u00a0<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u5c06<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">1.2 g<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u6b63\u4e01\u9178<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">(C<sub style=\"margin: 0px;padding: 0px;max-width: 100%\">3<\/sub>H<sub style=\"margin: 0px;padding: 0px;max-width: 100%\">5<\/sub>NO)<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u878d\u89e3\u5728\u53bb\u79bb\u5b50\u6c34<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">(10 ml)<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u4e2d\uff0c\u6dfb\u52a0<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">6 mg<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u7684<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">N,N\\&#8217;-<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u7532\u57fa\u53cc\u4e19\u70ef\u9170\u80fa<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">(C<sub style=\"margin: 0px;padding: 0px;max-width: 100%\">7<\/sub>H<sub style=\"margin: 0px;padding: 0px;max-width: 100%\">10<\/sub>N<sub style=\"margin: 0px;padding: 0px;max-width: 100%\">2<\/sub>O<sub style=\"margin: 0px;padding: 0px;max-width: 100%\">2<\/sub>)<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u548c<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">20<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u03bc<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">L\u00a0<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u7684<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">N,N,N\\&#8217;<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\uff0c<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">N\\&#8217;-<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u56db\u7f9f\u57fa\u4e59\u80fa<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">(C<sub style=\"margin: 0px;padding: 0px;max-width: 100%\">6<\/sub>H<sub style=\"margin: 0px;padding: 0px;max-width: 100%\">16<\/sub>N<sub style=\"margin: 0px;padding: 0px;max-width: 100%\">2<\/sub>)<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u3002<\/p>\n<p><strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u00a0 \u00a0 \u00a0 \u00a0\u2461\u00a0\u00a0<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u4ea7\u751f\u5168\u900f\u660e\u6ca1\u6709\u989c\u8272\u9971\u548c\u6eb6\u6db2\u540e\uff0c\u518d\u6dfb\u52a0<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">7mg<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u8fc7\u6c27\u5316\u7269\u786b\u9178\u94f5\u3002\u6240\u5f97\u7684\u51dd\u80f6\u5242\u7ecf\u5e72\u51bb\u9664\u53bb\u5438\u9644\u540e\uff0c\u6ce1\u6d78\u5728\u542b<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">NaCl<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u548c<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">ZnCl<sub style=\"margin: 0px;padding: 0px;max-width: 100%\">2<\/sub><strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u7684\u6eb6\u6db2\u4e2d\u80c0\u5927\u3002<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">(<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u51dd\u80f6\u5242\u3001<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">NaCl<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u3001<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">ZnCl<sub style=\"margin: 0px;padding: 0px;max-width: 100%\">2<\/sub><strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u7684\u8d28\u91cf\u6bd4\u4e3a<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">1:1:1)<\/p>\n<p><strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u00a0 \u00a0 \u00a0 \u00a0\u2462\u00a0\u00a0<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u590d\u5408\u578b\u5e72\u51bb<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">,<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u63a5\u7740\u52a0\u6e29\u5230<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">300\u00b0C<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u771f\u7a7a\u70d8\u7bb1N2\u6d41\u52a8\u6027<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">,<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u5e76\u4fdd\u6301\u5728<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">300\u00b0C 1 h<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u3002\u4ee5\u540e\u6eab\u5ea6\u63d0\u5347\u5230<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">600\u00b0C\u00a0\u00a0<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u5e76\u4fdd\u6301\u5728<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">600\u00b0C2 h<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u3002<\/p>\n<p><strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u00a0 \u00a0 \u00a0 \u00a0\u2463\u00a0\u00a0<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u6700\u7ec8\uff0c\u5546\u54c1\u5728<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">80\u2103<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u7684\u771f\u7a7a\u5e72\u71e5\u5668\u4e2d\u5e72\u8e81<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">24<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u949f\u5934\uff0c\u6240\u5f97\u7684\u7c89\u672b\u72b6\u4e3a\u5206\u5c42\u6b21\u591a\u5b54\u7ed3\u6784\u78b3<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">(HPC)<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u3002\u5728\u5f02\u4e19\u9187\u7684\u4f5c\u7528\u4e0b\uff0c\u5c06<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">HPC<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u7c89\u548c\u805a\u56db\u6c1f\u4e59\u70ef\u6309\u51c0\u91cd\u6bd4\u4e3a<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">8:2<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u7f29\u5c0f\uff0c\u5236\u53d6<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">HDHPC<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u9632\u62a4\u5c42\u3002\u5c06\u83b7\u5f97\u7684\u819c\u5207\u5272\u6210\u76f4\u5f91\u4e3a<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">14mm<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u7684\u819c\u3002<\/p>\n<p><strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u9502\u6c14\u4f53<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">(O2)<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u9502\u7535\u6c60\u7ec4\u4ef6<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">:<\/p>\n<p><strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u9502\u7535\u6c60\u7ec4\u4ef6\u662f\u5728\u4e00\u4e2a\u5145\u6ee1\u4e86\u6c29\u7684\u6276\u624b\u7bb1\u4e2d\u5b9e\u9645\u64cd\u4f5c\u7684\u3002\u9009\u7528\u73bb\u7ea4\u8188\u819c<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u6d78\u6db2<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">(1 M LiTFSI\/TEGDME)<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u5206\u79bb\u51fa\u6765<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">Ru-CNTs<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u6b63\u7ea7\u548c<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">Li<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u91d1\u5c5e\u6750\u6599\u8d1f\u7ea7\u3002<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">HDHPC<strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u9632\u62a4\u5c42\u7acb\u5373\u906e\u76d6\u5728\u91d1\u5c5e\u9502\u9633\u6781\u6c27\u5316\u8868\u5c42\uff0c\u6e17\u5165\u9502\u7535\u6c60\u7535\u89e3\u6db2\u3002<\/p>\n<p><strong style=\"margin: 0px;padding: 0px;max-width: 100%\"><br style=\"margin: 0px;padding: 0px;max-width: 100%\" \/><\/p>\n<p><strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u3010\u56fe\u6587\u5e76\u8302\u9009\u53d6\u3011<\/p>\n<p><img decoding=\"async\" src=\"\/wp-content\/uploads\/2021\/12\/20211215142155-61b9fa03061fc.jpg\" title=\"3.jpg\" alt=\"3.jpg\" \/><\/p>\n<p>Figure 1. Characterization of the HDHPC protective layer. (a) Photograph of an achieved HDHPC protective layer. (b) SEM image of the HDHPC protective layer. (c) Contact angle of H<sub style=\"margin: 0px;padding: 0px;max-width: 100%\">2<\/sub>O on the HDHPC protective layer. (d) Nitrogen adsorption-desorption isotherms and pore-size distribution (inset) of the HDHPC protective layer. (e) N 1s and (f) O 1s XPS spectra of the HDHPC protective layer.<\/p>\n<p><br style=\"margin: 0px;padding: 0px;max-width: 100%\" \/><\/p>\n<p><img decoding=\"async\" src=\"\/wp-content\/uploads\/2021\/12\/20211215142155-61b9fa0341519.jpg\" title=\"4.jpg\" alt=\"4.jpg\" \/><\/p>\n<p>Figure 2. Electrochemical performance of the Li-air (O<sub style=\"margin: 0px;padding: 0px;max-width: 100%\">2<\/sub>) battery. Recyclability of the Li-air battery in ambient air (a) with and (b) without the HDHPC protective layer. Recyclability of Li-O<sub style=\"margin: 0px;padding: 0px;max-width: 100%\">2<\/sub>\u00a0batteryin pure O<sub style=\"margin: 0px;padding: 0px;max-width: 100%\">2\u00a0<\/sub>condition (c) with and (d) without the HDHPC protective layer. Cutoff capacity: 1000 mA h g<sup style=\"margin: 0px;padding: 0px;max-width: 100%\">-1<\/sup>. Current density: 500 mA g<sup style=\"margin: 0px;padding: 0px;max-width: 100%\">-1<\/sup>.<\/p>\n<p><br style=\"margin: 0px;padding: 0px;max-width: 100%\" \/><\/p>\n<p><img decoding=\"async\" src=\"\/wp-content\/uploads\/2021\/12\/20211215142155-61b9fa036f41f.jpg\" title=\"5.jpg\" alt=\"5.jpg\" \/><\/p>\n<p>Figure 3. Examination of lithium metal anode in Li-air (O<sub style=\"margin: 0px;padding: 0px;max-width: 100%\">2<\/sub>) batteries. SEM image of (a) the pristine lithium metal anode, lithium metal anode (b) without and (c) with the HDHPC protective layer coating in Li-air batteries after the 20th cycle. SEM image of (d) the pristine lithium metal anode, lithium metal anode (e) without and (f) with the HDHPC protective layer coating in Li-O<sub style=\"margin: 0px;padding: 0px;max-width: 100%\">2\u00a0<\/sub>batteries after the 20th cycle. (g) Ex situ XRD patterns of the lithium metal anode with (or without) the HDHPC protective layer coating in Li-air batterie safter the 5th cycle. (h) EIS plots of the Li-air battery with (or without) the HDHPC protective layer coating at the pristine stage (inset) and after the 5th cycle.<\/p>\n<p><br style=\"margin: 0px;padding: 0px;max-width: 100%\" \/><\/p>\n<p><img decoding=\"async\" src=\"\/wp-content\/uploads\/2021\/12\/20211215142155-61b9fa03a28ca.jpg\" title=\"6.jpg\" alt=\"6.jpg\" \/><\/p>\n<\/p>\n<p>Figure 4. Investigation of Ru-CNT cathodes in Li-air (O<sub style=\"margin: 0px;padding: 0px;max-width: 100%\">2<\/sub>) batteries containing the HDHPC protective layer. SEM images of (a) pristine, (b) discharged, and (c) recharged Ru-CNT cathodes in HDHPC protective layer-based Li-air batteries. (d) Ex situ XRD patterns and (e) ex situ FTIR spectra of pristine, discharged, and recharged Ru-CNT cathodes in the HDHPC protective layer-based Li-air batteries. Charge curves and corresponding gas evolution of the (f) Li-O<sub style=\"margin: 0px;padding: 0px;max-width: 100%\">2<\/sub>\u00a0cell and (g) Li-air cell with the HDHPC protective layer at 500 mA g<sup style=\"margin: 0px;padding: 0px;max-width: 100%\">-1<\/sup>.<\/p>\n<p><br style=\"margin: 0px;padding: 0px;max-width: 100%\" \/><\/p>\n<p><strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u3010\u5173\u952e\u7ed3\u679c\u3011<\/p>\n<p><strong style=\"margin: 0px;padding: 0px;max-width: 100%\">\u6587\u4e2d\u6839\u636e\u5728\u73af\u5883\u8d28\u91cf\u548c\u6c27\u6c14\u6807\u51c6\u4e0b\uff0c\u8bc1\u5b9eHDHPC\u9632\u62a4\u5c42\u662f\u9502\u91d1\u5c5e\u6750\u6599\u8d1f\u7ea7\u7684\u4f18\u8d28\u9632\u62a4\u5c42\uff0c\u8fd9\u7c7b\u819c\u786e\u4fdd\u4e86\u957f\u671f\u6027\u8fd0\u4f5c\u7684\u9502\u91d1\u5c5e\u6750\u6599\u8d1f\u7ea7\u7684\u65e0\u679d\u6676\u5f62\u72b6\u3002\u5728\u73af\u5883\u8d28\u91cf\u4e2d\uff0c\u4e0e\u6c92\u6709HDHPC\u9632\u62a4\u5c42\u7684\u5145\u7535\u7535\u6c60\u5bf9\u6bd4\uff0c\u8be5\u9502\u7a7a\u6c14\u7535\u6c60\u5177\u5907\u66f4\u957f\u7684\u5faa\u73af\u7cfb\u7edf\u4f7f\u7528\u5bff\u547d\u3002\u6b8a\u4e0d\u77e5\uff0c\u56e0\u4e3a\u8d1f\u7ea7\u949d\u5316\u548c\u8fdb\u653b\u7a7a\u6c14\u7684\u4f5c\u7528\uff0c\u73b0\u9636\u6bb5\u7684\u9502-\u7a7a\u6c14\u7535\u6c60\u7684\u5149\u7535\u50ac\u5316\u7279\u6027\u4f9d\u7136\u8fdc\u8fdc\u5730\u5c0f\u4e8e\u9502-o2\u5145\u7535\u7535\u6c60\u3002\u4e0b\u4e00\u6b65\u9664\u5f00\u7ef4\u62a4\u9502\u91d1\u5c5e\u6750\u6599\u8d1f\u7ea7\u5916\uff0c\u6291\u6b62\u6b63\u7ea7\u9502\u7a7a\u6c14\u7535\u6c60\u7684\u526f\u4f5c\u7528\u4e5f\u662f\u4e0d\u53ef\u6216\u7f3a\u7684\u3002<\/p>\n<p style=\"line-height: 2em\"><strong style=\"margin: 0px;padding: 0px;max-width: 100%\"><\/p>\n<p><\/p>\n<p>&nbsp;<\/p>\n<p><span style=\"font-size: 8pt;color: #999999\"><em>         \u8be5\u6587\u7ae0\u5185\u5bb9\u81f4\u529b\u4e8e\u6563\u64ad\u65b0\u6280\u672f\u5e94\u7528\u65b0\u95fb\u8d44\u8baf\uff0c\u5f88\u6709\u53ef\u80fd\u6709\u8f6c\u622a\/\u5f15\u5165\u4e4b\u72b6\u51b5\uff0c\u82e5\u6709\u4fb5\u6743\u884c\u4e3a\u8bf7\u8054\u7edc\u5220\u6389\u3002<\/em><\/span><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u8bba\u6587\u94fe\u63a5\u3011https:\/\/dx.doi.org\/10.1021\/acsami.0c05494\u3010\u4f5c\u8005\u5355\u4f4d\u3011FudanUniversity\u3010\u8bba\u6587\u6458\u8981\u3011\u672c\u6587\u62a5\u9053\u4e86\u5177\u6709\u8d85\u758f\u6c34\u6027\u7684\u6c34\u51dd\u80f6\u884d\u751f\u7684\u5206\u5c42\u591a\u5b54\u78b3(HDHPC)\u5c42\u88ab\u8bc1\u660e\u662f\u9502\u7a7a\u6c14\u7535\u6c60\u7684\u6709\u6548\u9502\u4fdd\u62a4\u5c42\uff0c\u5176\u53ef\u4ee5\u6291\u5236\u5faa\u73af\u8fc7\u7a0b\u4e2d<\/p>\n","protected":false},"author":1,"featured_media":25754,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[59],"tags":[],"class_list":["post-25755","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-industry-information"],"jetpack_featured_media_url":"\/wp-content\/uploads\/2021\/12\/20211215142155-61b9fa03da6f8.jpg","jetpack-related-posts":[{"id":31872,"url":"https:\/\/www.paiqinano.com\/?p=31872","url_meta":{"origin":25755,"position":0},"title":"\u9502\u7535\u6c60\u63a7\u5236\u677f\u9632\u6f6e\u9632\u7535\u89e3\u6db2\u8150\u8680\u7eb3\u7c73\u6d82\u5c42\u6750\u6599\uff1a\u65b0\u4e00\u4ee3\u5b89\u5168\u6027\u80fd\u5347\u7ea7","author":"\u6d3e\u65d7\u7eb3\u7c73","date":"2023\u5e745\u670825\u65e5","format":false,"excerpt":"\u968f\u7740\u79d1\u6280\u7684\u4e0d\u65ad\u53d1\u5c55\u548c\u8fdb\u6b65\uff0c\u9502\u7535\u6c60\u5df2\u7ecf\u6210\u4e3a\u6211\u4eec\u65e5\u5e38\u751f\u6d3b\u4e2d\u4e0d\u53ef\u6216\u7f3a\u7684\u80fd\u6e90\u5b58\u50a8\u88c5\u7f6e\u3002\u65e0\u8bba\u662f\u624b\u673a\u3001\u7b14\u8bb0\u672c\u7535\u8111\u2026","rel":"","context":"\u5728\u201c\u884c\u4e1a\u8d44\u8baf\u201d\u4e2d","block_context":{"text":"\u884c\u4e1a\u8d44\u8baf","link":"https:\/\/www.paiqinano.com\/?cat=59"},"img":{"alt_text":"","src":"\/wp-content\/uploads\/2023\/05\/29130af44aaae10baf33a87f063f170-1.jpg","width":350,"height":200},"classes":[]},{"id":31132,"url":"https:\/\/www.paiqinano.com\/?p=31132","url_meta":{"origin":25755,"position":1},"title":"\u7eb3\u7c73\u6d82\u5c42\u56fd\u9645\u65b0\u95fb\uff1a\u6fb3\u5927\u5229\u4e9a\u7814\u53d1\u65b0\u578b\u7eb3\u7c73\u6d82\u5c42\u53ef\u5ef6\u957f\u9502\u7535\u6c60\u4f7f\u7528\u5bff\u547d","author":"\u6d3e\u65d7\u7eb3\u7c73","date":"2022\u5e745\u670830\u65e5","format":false,"excerpt":"\u6fb3\u5927\u5229\u4e9a\u6606\u58eb\u5170\u5927\u5b66\u7684\u7814\u7a76\u4eba\u5458\u5f00\u53d1\u51fa\u4e00\u79cd\u65b0\u578b\u7eb3\u7c73\u6d82\u5c42\uff0c\u53ef\u4ee5\u5ef6\u957f\u9502\u7535\u6c60\u7684\u4f7f\u7528\u5bff\u547d\uff0c\u964d\u4f4e\u5e9f\u7535\u6c60\u7684\u73af\u5883\u5371\u5bb3\u3002\u2026","rel":"","context":"\u5728\u201c\u7eb3\u7c73\u79d1\u5b66\u9886\u57df\u62a5\u9053\u201d\u4e2d","block_context":{"text":"\u7eb3\u7c73\u79d1\u5b66\u9886\u57df\u62a5\u9053","link":"https:\/\/www.paiqinano.com\/?cat=58"},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":18221,"url":"https:\/\/www.paiqinano.com\/?p=18221","url_meta":{"origin":25755,"position":2},"title":"12\u4f0f\u7684\u9502\u7535\u6c60\u7684\u5e94\u7528\u53ca\u6ce8\u610f\u4e8b\u9879\u8bf4\u660e","author":"\u6d3e\u65d7\u7eb3\u7c73","date":"2022\u5e742\u67089\u65e5","format":false,"excerpt":"12v\u9502\u7535\u6c60\u4fdd\u62a4\u677f\u662f\u7535\u6c60\u4fdd\u62a4\u7535\u8def\u677f\uff0c\u4e00\u822c\u7528\u4e8e\u5927\u5bb9\u91cf12v\u9502\u7535\u6c60\u7ec4\uff0c\u5177\u6709\u8fc7\u5145\uff0c\u8fc7\u653e\uff0c\u8fc7\u6d41\uff0c\u77ed\u8def\uff0c\u7535\u6c60\u5e73\u2026","rel":"","context":"\u5728\u201c\u884c\u4e1a\u8d44\u8baf\u201d\u4e2d","block_context":{"text":"\u884c\u4e1a\u8d44\u8baf","link":"https:\/\/www.paiqinano.com\/?cat=59"},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":20297,"url":"https:\/\/www.paiqinano.com\/?p=20297","url_meta":{"origin":25755,"position":3},"title":"PCB\u954d\u9540\u6db2\u4f7f\u7528\u5e38\u4f1a\u9047\u5230\u90a3\u4e9b\u95ee\u9898\uff1f","author":"\u6d3e\u65d7\u7eb3\u7c73","date":"2022\u5e741\u670812\u65e5","format":false,"excerpt":"PCB\u4f4e\u5e94\u529b\u954d\u7684\u6dc0\u79ef\u5c42\uff0c\u901a\u5e38\u662f\u7528\u6539\u6027\u578b\u7684\u74e6\u7279\u954d\u9540\u6db2\u548c\u5177\u6709\u964d\u4f4e\u5e94\u529b\u4f5c\u7528\u7684\u6dfb\u52a0\u5242\u7684\u4e00\u4e9b\u6c28\u57fa\u78fa\u9178\u954d\u9540\u6db2\u6765\u9540\u2026","rel":"","context":"\u5728\u201c\u884c\u4e1a\u8d44\u8baf\u201d\u4e2d","block_context":{"text":"\u884c\u4e1a\u8d44\u8baf","link":"https:\/\/www.paiqinano.com\/?cat=59"},"img":{"alt_text":"","src":"\/wp-content\/uploads\/2021\/12\/20211215131508-61b9ea5ca01ab.jpeg","width":350,"height":200},"classes":[]},{"id":30578,"url":"https:\/\/www.paiqinano.com\/?p=30578","url_meta":{"origin":25755,"position":4},"title":"\u3010\u79d1\u6280\u53d1\u73b0\u3011\u5fb7\u56fd\u65b0\u7814\u7a76\uff1a\u56fa\u6001\u7535\u6c60\u754c\u9762\u6d82\u8986\u7eb3\u7c73\u6d82\u5c42\u53ef\u8ba9\u7535\u6c60\u7a33\u5b9a","author":"\u6d3e\u65d7\u7eb3\u7c73","date":"2022\u5e743\u67081\u65e5","format":false,"excerpt":"\u56fa\u6001\u7535\u6c60\u4e2d\u7684\u79bb\u5b50\u9700\u8981\u5728\u591a\u5c42\u6750\u6599\u754c\u9762\u4e2d\u7a7f\u884c\uff0c\u800c\u8fd9\u4f1a\u5e26\u6765\u4e00\u4e9b\u6311\u6218\u3002\u636e\u5916\u5a92\u62a5\u9053\uff0c\u5fb7\u56fd\u6155\u5c3c\u9ed1\u5de5\u4e1a\u5927\u5b66\u51ef\u6492\u00b7\u5a01\u2026","rel":"","context":"\u5728\u201c\u884c\u4e1a\u8d44\u8baf\u201d\u4e2d","block_context":{"text":"\u884c\u4e1a\u8d44\u8baf","link":"https:\/\/www.paiqinano.com\/?cat=59"},"img":{"alt_text":"","src":"\/wp-content\/uploads\/2022\/03\/\u5fae\u4fe1\u622a\u56fe_20230721143850.png","width":350,"height":200},"classes":[]},{"id":17347,"url":"https:\/\/www.paiqinano.com\/?p=17347","url_meta":{"origin":25755,"position":5},"title":"\u7b80\u8981\u4ecb\u7ecd\u9502\u7535\u6c60,\u9502\u7535\u6c60\u5b89\u5168\u6848\u4f8b\u5206\u6790","author":"\u6d3e\u65d7\u7eb3\u7c73","date":"2022\u5e741\u670816\u65e5","format":false,"excerpt":"\u9502\u7535\u6c60\u7684\u7535\u82af\u662f\u7535\u6c60\u7684\u6838\u5fc3\u90e8\u4ef6\uff0c\u662f\u51b3\u5b9a\u7535\u6c60\u54c1\u8d28\u7684\u6700\u6839\u672c\u56e0\u7d20\uff0c\u5bf9\u6280\u672f\u3001\u751f\u4ea7\u6d41\u7a0b\u7ba1\u63a7\u53ca\u539f\u6750\u6599\u54c1\u8d28\u8981\u6c42\u6781\u9ad8\u3002\u2026","rel":"","context":"\u5728\u201c\u884c\u4e1a\u8d44\u8baf\u201d\u4e2d","block_context":{"text":"\u884c\u4e1a\u8d44\u8baf","link":"https:\/\/www.paiqinano.com\/?cat=59"},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]}],"_links":{"self":[{"href":"https:\/\/www.paiqinano.com\/index.php?rest_route=\/wp\/v2\/posts\/25755","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.paiqinano.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.paiqinano.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.paiqinano.com\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.paiqinano.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=25755"}],"version-history":[{"count":1,"href":"https:\/\/www.paiqinano.com\/index.php?rest_route=\/wp\/v2\/posts\/25755\/revisions"}],"predecessor-version":[{"id":26426,"href":"https:\/\/www.paiqinano.com\/index.php?rest_route=\/wp\/v2\/posts\/25755\/revisions\/26426"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.paiqinano.com\/index.php?rest_route=\/wp\/v2\/media\/25754"}],"wp:attachment":[{"href":"https:\/\/www.paiqinano.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=25755"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.paiqinano.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=25755"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.paiqinano.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=25755"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}