{"id":23830,"date":"2021-12-23T10:49:58","date_gmt":"2021-12-23T02:49:58","guid":{"rendered":"https:\/\/www.paiqinano.com\/?p=23830"},"modified":"2021-12-22T15:08:17","modified_gmt":"2021-12-22T07:08:17","slug":"%e6%97%a0%e8%a7%86%e7%8e%8b%e6%b0%b4%e5%92%8c%e7%83%a7%e7%a2%b1%ef%bc%8c%e8%bf%98%e5%be%88%e5%bc%ba%e9%9f%a7-nat-mater-%e5%b0%81%e9%9d%a2%e4%b8%8a%e7%9a%84%e5%85%a8%e6%9c%89%e6%9c%ba","status":"publish","type":"post","link":"https:\/\/www.paiqinano.com\/?p=23830","title":{"rendered":"Nat. Mater.\u5c01\u9762\u4e0a\u7684\u5168\u6709\u673a\u8d85\u758f\u6c34\u6d82\u5c42\u4e86\u89e3\u4e00\u4e0b\uff1f"},"content":{"rendered":"

\u00a0\u8d85\u758f\u6c34\u72b6\u51b5\u5728\u81ea\u7136\u4e2d\u666e\u904d\u5b58\u6709\uff0c\u83cf\u53f6\u3001\u8774\u8776\u7fc5\u8180\u53ca\u5176\u4e00\u4e9b\u6606\u866b\u7684\u673a\u58f3\uff0c\u90fd\u5c55\u73b0\u8d85\u758f\u6c34\u60c5\u51b5\u3002\u4f34\u968f\u7740\u5bf9\u8d85\u758f\u6c34\u8868\u73b0\u672c\u8d28\u539f\u7406\u79d1\u5b66\u7814\u7a76\u7684\u9010\u6b65\u63a8\u8fdb\uff0c\u5927\u5bb6\u53d1\u89c9\u4ea7\u54c1\u8868\u5c42\u7684\u7269\u7406\u6027\u8d28\u548c\u5916\u90e8\u7ecf\u6d4e\u6784\u9020\u662f\u5305\u542b\u5149\u50ac\u5316\u5242\u60c5\u51b5\u76842\u4e2a\u4e3b\u8981\u56e0\u7d20\u3002\u56e0\u4e3a\u8d85\u758f\u6c34\u72b6\u51b5\u53ef\u4ee5\u7528\u4ee5\u81ea\u6e05\u7406\u3001\u8010\u6c61\u3001\u9632\u7ed3\u51bb\u3001\u6cb9\u6c34\u5206\u79bb\u5668\u7b49\u8bb8\u591a\u884c\u4e1a\uff0c\u751f\u7269\u5b66\u5bb6\u4e00\u76f4\u5728\u5f00\u53d1\u8bbe\u8ba1\u5404\u79cd\u5404\u6837\u7684\u8d85\u758f\u6c34\u539f\u6750\u6599\u548c\u9540\u5c42\u3002\u6839\u636e\u6709\u673a\u5316\u5b66\/\u6709\u673a\u7269\uff08\u7eb3\u7c73\u9897\u7c92\uff09\u5939\u6742\u3001\u5f15\u8fdb\u6da6\u5316\u5c42\u3001\u6784\u5efa\u5fae\/\u7eb3\u590d\u5408\u578b\u7cbe\u7ec6\u7ed3\u6784\u5916\u89c2\u7b49\u4f17\u591a\u65b9\u5f0f\u65e9\u5df2\u5e7f\u6cdb\u8fd0\u7528\u4e8e\u5f62\u72b6\u8bb0\u5fc6\u539f\u6750\u6599\u548c\u9540\u5c42\u7684\u5236\u53d6\uff0c\u5728\u5176\u4e2d\u4e00\u4e9b\u6216\u8010\u78e8\u6027\u4f18\u5f02\uff0c\u6216\u7535\u5316\u5b66\u53ef\u9760\u6027\u51fa\u8272\uff0c\u6216\u4e0e\u677f\u6750\u9ecf\u9644\u6027\u4e0d\u9519\uff0c\u6216\u4f7f\u7528\u671f\u9650\u957f\u3002\u4f46\u662f\uff0c\u4e0e\u6b64\u540c\u65f6\u517c\u987e\u4ee5\u4e0a\u4f18\u52bf\u7684\u8d85\u758f\u6c34\u9540\u5c42\u5374\u975e\u5e38\u5c11\uff0c\u9664\u6b64\u4e4b\u5916\uff0c\u4e5f\u96be\u5f97\u5c11\u6709\u8d85\u758f\u6c34\u9540\u5c42\u53ef\u4ee5\u627f\u53d7\u5feb\u901f\u6db2\u6001\u51b2\u6d17\u3002<\/p>\n

\n

\u00a0 \u00a0 \u6784\u5efa\u6027\u80fd\u5353\u8d8a\u8d85\u758f\u6c34\u9540\u5c42\u5e38\u89c1\u7684\u5bf9\u7b56\u6709\u4e09\u79cd\uff1a\u6839\u636e\u4eff\u751f\u6280\u672f\u5bf9\u7b56\u6388\u4e88\u9540\u5c42\u81ea\u6062\u590d\u6027\u3001\u6784\u5efa\u8868\u9762\u4e0e\u5185\u90e8\u6784\u9020\u548c\u7279\u6027\u4e00\u81f4\u7684\u5747\u76f8\u9540\u5c42\u3001\u6784\u5efa\u8f6f\u6027\u9540\u5c42\u3002\u8fd1\u65e5\uff0c\u4f26\u6566\u5927\u5b66\u5b66\u6821\uff08UCL\uff09\u7684Manish K. Tiwari\u7814\u7a76\u7ec4\u5f00\u53d1\u5229\u7528\u4ee5\u4e0a\u5bf9\u7b56\u7684\u540e\u4e8c\u79cd\uff0c\u6784\u5efa\u4e86\u4e00\u79cd\u8f6f\u6027\u7684\u5168\u6709\u673a\u5316\u5b66\u7eb3\u7c73\u6280\u672f\u4e00\u6c27\u5316\u6c2e\u5408\u9176\u8d85\u758f\u6c34\u9540\u5c42\uff0c\u5728\u5176\u4e2d\u5305\u62ec\u6c1f\u5316\u6c22\u73af\u6c27\u6811\u8102\u80f6\u3001\u5168\u6c1f\u7532\u57fa\u4e19\u70ef\u9178\u916f\u548c\u542b\u6c1f\u91cf\u9ad8\u805a\u7269\u7eb3\u7c73\u9897\u7c92\u3002\u8be5\u9540\u5c42\u5c55\u793a\u51fa\u51fa\u8272\u7684\u8bbe\u5907\u53ef\u9760\u6027\uff0c\u53ef\u4ee5\u627f\u53d7\u4e25\u82db\u7684\u9508\u8680\u81ea\u7136\u73af\u5883\uff08\u6bd4\u5982\u786b\u9178\u548c\u6c22\u6c27\u5316\u94a0\u6eb6\u6db2\uff09\uff0c\u800c\u4e14\u53ef\u4ee5\u5408\u7406\u627f\u53d7\u5feb\u901f\u51fa\u6db2\u548c\u6d41\u6db2\u7684\u51b2\u51fb\u6027\u800c\u4e0d\u88ab\u6bc1\u574f\u548c\u900f\u8fc7\u3002\u4e0e\u6b64\u540c\u65f6\uff0c\u8fd9\u7c7b\u9540\u5c42\u53ef\u6839\u636e\u55b7\u6f06\u3001\u5237\u6d82\u7b49\u57fa\u672c\u65b9\u5f0f\u4f7f\u7528\u5728\u672a\u5904\u7406\u7684\u8868\u5c42\uff0c\u5b9e\u9645\u64cd\u4f5c\u975e\u5e38\u5bb9\u6613\u3002\u6709\u5173\u53d1\u8868\u8bba\u6587\u4e8eNature Materials \u5e76\u88ab\u8bc4\u4e3a\u5c01\u9762\u56fe\u6587\u7ae0\u5185\u5bb9\uff0c\u7b2c\u4e00\u4f5c\u8005\u4e3aChaoyi Peng\u3002<\/p>\n

\n

\"2.jpg\"<\/p>\n

\u672c\u671f\u5c01\u9762\u56fe\u3002\u56fe\u7247\u51fa\u5904\uff1aNat. Mater.<\/p>\n

\n

\u00a0 \u00a0 \u9540\u5c42\u6210\u5206\u7684\u6311\u9009\u548c\u7ec4\u6210\u8017\u8d39\u4e86\u5b66\u8005\u8bb8\u591a\u65f6\u95f4\u3002\u73af\u6c27\u6811\u8102\u80f6\u7684\u673a\u68b0\u8bbe\u5907\u548c\u6709\u673a\u5316\u5b66\u53ef\u9760\u6027\u6781\u4f73\uff0c\u6839\u636e\u4eb2\u6c34\u6027\u5b98\u80fd\u56e2\u5f02\u6784\u8fd8\u80fd\u5206\u6563\u5316\u7eb3\u7c73\u9897\u7c92\uff0c\u800c\u4e14\u5177\u5907\u5f3a\u52b2\u7684\u677f\u6750\u9ecf\u9644\u529b\uff1b\u5168\u6c1f\u7532\u57fa\u4e19\u70ef\u9178\u916f\u6709\u5229\u4e8e\u8c03\u8282\u9540\u5c42\u7684\u8868\u9762\u548c\u8f6f\u6027\uff1b\u542b\u6c1f\u91cf\u9ad8\u805a\u7269\u7eb3\u7c73\u9897\u7c92\u53ef\u4ee5\u7ed9\u4e88\u6784\u9020\u64cd\u7eb5\u5e76\u51cf\u5c11\u8868\u9762\u3002\u4f46\u662f\u4e00\u822c\u7684\u73af\u6c27\u6811\u8102\u80f6\u672a\u6539\u6027\u6750\u6599\u524d\u8868\u5c42\u6c34\u8868\u9762\u5f20\u529b\uff08WCA\uff09\u7ea643\u00b0\uff08\u4e0b\u9762\u7684\u56fea\uff09\uff0c\u8fd9\u7c7b\u758f\u6c34\u6027\u663e\u800c\u6613\u89c1\u6ca1\u6cd5\u6ee1\u8db3\u8981\u6c42\u3002\u5b66\u8005\u5e94\u7528\u201c\u591a\u6b65\u6c1f\u5316\u6c22\uff08multi-fluorination\uff09\u201d\u5bf9\u7b56\u6765\u5236\u53d6\u6027\u80fd\u5353\u8d8a\u8d85\u758f\u6c34\u9540\u5c42\u3002\u6700\u5148\uff0c\u5979\u4eec\u5e94\u7528\u542b\u6c1f\u91cf\u9ad8\u805a\u7269\u5bf9\u6811\u8102\u5f00\u5c55\u70ed\u805a\u5408\u6539\u6027\u6750\u6599\u83b7\u5f97\u6c1f\u5316\u6c22\u73af\u6c27\u6811\u8102\u80f6\uff08\u8bb0\u4f5cFE\uff09\uff0c\u4ee5\u63d0\u9ad8\u5176\u758f\u6c34\u6027\uff0cWCA\u63d0\u5347\u5230\u7ea680\u00b0\uff08\u4e0b\u9762\u7684\u56feb\uff09\u3002\u5979\u4eec\u5728\u6c1f\u5316\u6c22\u73af\u6c27\u6811\u8102\u80f6\u4e2d\u6e17\u5165\u5168\u6c1f\u7532\u57fa\u4e19\u70ef\u9178\u916f\uff08Krytox oil\uff09\uff0c\u6388\u4e88\u73af\u6c27\u6811\u8102\uff08\u8bb0\u4f5cKFE\uff09\u51fa\u8272\u7684\u8f6f\u6027\uff0c\u4e0e\u6b64\u540c\u65f6\u8fdb\u4e00\u6b65\u63d0\u5347\u758f\u6c34\u6027\uff0cWCA\u63d0\u5347\u5230\u7ea693\u00b0\uff08\u4e0b\u9762\u7684\u56fec\uff09\u3002\u800c\u540e\uff0c\u6839\u636e\u6dfb\u52a0\u542b\u6c1f\u91cf\u9ad8\u805a\u7269\uff08\u805a\u56db\u6c1f\u4e59\u70ef\uff0cPTFE\uff09\u7eb3\u7c73\u9897\u7c92\uff0c\u6240\u5f97\u7684\u8d85\u758f\u6c34\u7eb3\u7c73\u6280\u672f\u4e00\u6c27\u5316\u6c2e\u5408\u9176\u9540\u5c42\uff08\u8bb0\u4f5cPKFE\uff09\u7684WCA\u63d0\u9ad8\u81f3\u7ea6158\u00b0\uff08\u4e0b\u9762\u7684\u56fed\uff09\u3002\u5b66\u8005\u6839\u636e\u5085\u91cc\u53f6\u53d8\u6362\u7ea2\u5916\u5149\u8c31\u5bf9\u591a\u6b65\u6c1f\u5316\u6c22\u5bf9\u7b56\u7684\u6bcf\u4e2a\u5168\u8fc7\u7a0b\u6240\u5f97\u7684\u5546\u54c1\u5f00\u5c55\u4e86\u76f8\u5bf9\u7684\u8868\u73b0\uff08\u4e0b\u9762\u7684\u56fee\uff09\uff0c\u7d50\u679c\u8bc1\u5b9e\u4e86\u4e8c\u6c1f\u7f9f\u57fa\u548c\u4e09\u6c1f\u7f9f\u57fa\u7684\u5b58\u6709\uff0c\u800c\u4e14\u6bcf\u4e00\u6b65\u7684\u6c1f\u5316\u6c22\u5168\u8fc7\u7a0b\u90fd\u5f88\u53d6\u5f97\u6210\u529f\u3002<\/p>\n

\n

\"3.jpg\"<\/p>\n

\u8d85\u758f\u6c34\u9540\u5c42\u6784\u5efa\u5168\u8fc7\u7a0b\u5e73\u9762\u56fe\u3002\u56fe\u7247\u51fa\u5904\uff1aNat. Mater.<\/p>\n

\n

\u00a0 \u00a0 \u8fd9\u7c7b\u7eb3\u7c73\u6280\u672f\u4e00\u6c27\u5316\u6c2e\u5408\u9176\u9540\u5c42\u9664\u5f00\u5177\u5907\u4e0d\u9519\u7684\u758f\u6c34\u6027\uff0c\u8fd8\u5c55\u793a\u51fa\u51fa\u8272\u7684\u8bbe\u5907\u53ef\u9760\u6027\u3002\u901a\u8fc730\u6b21\u9ad8\u9ecf\u6027\u80f6\u5e03\u8131\u79bb\u68c0\u6d4b\u540e\uff08\u4e0b\u9762\u7684\u56fea\uff09\uff0c\u9540\u5c42\u8868\u5c42\u672a\u9020\u6210\u663e\u8457\u635f\u5bb3\uff0cWCA\uff08\u03b8A\uff09\u4ecd\u8d85\u8fc7155\u00b0\uff0c\u8868\u9762\u5f20\u529b\u843d\u540e\u4ecd\u4f4e\u4e8e5\u00b0\u3002\u9540\u5c42\u5728\u4e0d\u4e00\u6837\u8d1f\u8f7d\u60c5\u51b5\u4e0b\u5f00\u5c55100\u6b21\u5faa\u73af\u7cfb\u7edfTaber\u635f\u574f\u68c0\u6d4b\uff08\u4e0b\u9762\u7684\u56fed\uff09\uff0c\u9540\u5c42\u8584\u539a\u672a\u5c55\u73b0\u6025\u5267\u4e0b\u964d\uff0c\u9540\u5c42\u8868\u5c42\u4ecd\u5c55\u73b0\u826f\u597d\u7684\u758f\u6c34\u6027\uff08150 g\u8d1f\u8f7d\u4e0b\uff0c\u03b8A\u7ea6\u4e3a155\u00b0\uff1b200 g\u5408\u4e4e\u4e0b\uff0c\u03b8A\u7ea6\u4e3a151\u00b0\uff1b250?g\u8d1f\u8f7d\u4e0b\uff0c\u03b8A\u7ea6\u4e3a146\u00b0\uff09\u3002\u4e8c\u79cd\u68c0\u6d4b\u4e0b\uff0c\u9540\u5c42\u5916\u8c8c\u4e5f\u6ca1\u6709\u4ea7\u751f\u663e\u8457\u8f6c\u53d8\uff0c\u800c\u4e14\u9540\u5c42\u4e00\u81f4\u6027\u4e5f\u5f97\u5230\u7ef4\u6301\uff0c\u6c34\u73e0\u51b2\u51fb\u6027\u90fd\u53ef\u4ee5\u88ab\u5f7b\u5e95\u5f39\u79bb\u3002<\/p>\n

\n

\"4.jpg\"<\/p>\n

\u8d85\u758f\u6c34\u9540\u5c42\u673a\u68b0\u8bbe\u5907\u7a33\u5b9a\u6027\u6d4b\u8bd5\u3002\u56fe\u7247\u51fa\u5904\uff1aNat. Mater.<\/p>\n

\n

\u00a0 \u00a0 \u5b66\u8005\u8fdb\u4e00\u6b65\u5bf9\u8d85\u758f\u6c34\u9540\u5c42\u7684\u6709\u673a\u5316\u5b66\u53ef\u9760\u6027\u5f00\u5c55\u68c0\u6d4b\u3002\u9009\u7528\u786b\u9178\uff0860 min\uff09\u53ca\u5176NaOH\u9971\u548c\u6eb6\u6db2\uff081M\uff0c12h\uff09\u9884\u6d78\u540e\uff0c\u9540\u5c42\u4ecd\u4fdd\u6301\u7740\u8be6\u7ec6\u8868\u5c42\u5916\u8c8c\u548c\u8d85\u758f\u6c34\u7279\u70b9\u3002<\/p>\n

\n

\"5.jpg\"<\/p>\n

\u8d85\u758f\u6c34\u9540\u5c42\u6709\u673a\u5316\u5b66\u7a33\u5b9a\u6027\u6d4b\u8bd5\u3002\u56fe\u7247\u51fa\u5904\uff1aNat. Mater.<\/p>\n

\n

\u00a0 \u00a0 \u9664\u6b64\u4e4b\u5916\uff0c\u8fd9\u7c7b\u8d85\u758f\u6c34\u9540\u5c42\u53ef\u4ee5\u627f\u53d7\u5feb\u901f\u51fa\u6db2\u548c\u6d41\u6db2\u7684\u51b2\u51fb\u6027\u800c\u4e0d\u88ab\u6bc1\u574f\u548c\u900f\u8fc7\u3002\u5728\u901f\u7387\u8fbe\u523035 m?s-1\u6d41\u6c34\u55b7\u51fa\u68c0\u6d4b\uff08\u97e6\u4f2f\u6570\uff1f43000\uff09\u4e2d\uff0c\u9540\u5c42\u8868\u5c42\u6784\u9020\u5e76\u6c92\u6709\u89c2\u67e5\u5230\u6709\u663e\u8457\u635f\u5bb3\uff0c\u5bf9\u6bd4\u4e8e\u8fc7\u53bb\u7684\u8d85\u758f\u6c34\u9540\u5c42\u5176\u9632\u6db2\u6001\u51b2\u6d17\u7279\u6027\u63d0\u5347\u4e86\u7c7b\u4f3c1\u4e2a\u91cf\u7ea7\u3002\u9664\u6b64\u4e4b\u5916\uff0c\u8fd9\u7c7b\u9540\u5c42\u7684\u8f6f\u6027\u4e5f\u4f7f\u5176\u53ef\u4ee5\u65bd\u7528\u4ee5\u8f6f\u6027\u539f\u6750\u6599\u8868\u5c42\uff0c\u8fdb\u4e00\u6b65\u6269\u5f20\u4e86\u5b83\u7684\u8fd0\u7528\u8303\u7574\u3002<\/p>\n

\n

\"6.jpg\"<\/p>\n

\u8d85\u758f\u6c34\u9540\u5c42\u627f\u53d7\u5feb\u901f\u51fa\u6db2\u548c\u6d41\u6db2\u7684\u51b2\u51fb\u6027\u3002\u56fe\u7247\u51fa\u5904\uff1aNat. Mater.<\/p>\n

\n

\"7.gif\"<\/p>\n

\u2014\u2014\u6c47\u603b\u2014\u2014<\/p>\n

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