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mV\u3002\u4e3a\u4e86\u66f4\u597d\u5730\u68c0\u6d4b\u5404\u8bd5\u4ef6\u7684\u5b8f\u89c2\u7ecf\u6d4e\u8010\u8150\u8680\u6027\u80fd\uff0c\u5728\u6d53\u5ea6\u503c\uff08\u8d28\u91cf\u6d53\u5ea6\uff09\u4e3a3.5%\u7684NaCl\u9971\u548c\u6eb6\u6db2\u4e2d\u5f00\u5c55168 h\u7684\u6ce1\u6d78\u8bd5\u9a8c\u3002<\/p>\n<p style=\"margin-top: 0px; margin-bottom: 10px; text-align: justify; line-height: 2em;\">2 \u7d50\u679c\u548c\u63a2\u8ba8<\/p>\n<p style=\"margin-top: 0px; margin-bottom: 10px; text-align: justify; line-height: 2em;\">2.1 \u9540\u5c42\u5916\u8c8c\u548c\u6da6\u6ed1\u6027<\/p>\n<p style=\"margin-top: 0px; margin-bottom: 10px; text-align: justify; line-height: 2em;\">\u56fe1\u5f97\u51fa\u4e86\u4e0d\u4e00\u6837\u89e3\u51b3\u540e\u94dd\u9541\u5408\u91d1\u7684\u8868\u5c42\u5916\u8c8c\u548c\u8868\u9762\u5f20\u529b\u3002\u4ece\u56fe1a\u53ef\u4ee5\u770b\u5f97\u51fa\uff0c\u5fae\u5f27\u6c27\u5316\u819c\u5c42\u8868\u5c42\u6709\u8bf8\u591a\u5c3a\u5bf8\u4e0d\u5300\u79f0\u7684\u5fae\u5b54\u677f\uff0c\u76f4\u5f84\u8303\u7574\u572810-50 \u03bcm,\u5fae\u5b54\u677f\u5468\u8fb9\u904d\u5e03\u7740\u7a81\u8d77\u7269\u3002\u8fd9\u7c7b\u591a\u5b54\u7ed3\u6784\u4e0d\u5149\u6ed1\u6784\u9020\u4e3b\u8981\u662f\u7531\u5145\u653e\u7535\u4e00\u77ac\u95f4\u9020\u6210\u7684\u9ad8\u6eab\u7194\u5316\u91d1\u5c5e\u6c27\u5316\u7269\u5236\u51b7\u51dd\u56fa\u4ea7\u751f\u7684[18],\u819c\u5c42\u4e0e\u7eaf\u51c0\u6c34\u7684\u8868\u9762\u5f20\u529b\u4e3a30\u00b0\uff0c\u4e3b\u8981\u8868\u73b0\u4e3a\u8d85\u5438\u6c34\u6027\u3002\u7ecf\u805a\u919a\u6d82\u6577\u540e\uff0c\u5fae\u5f27\u6c27\u5316\u7684\u5fae\u5b54\u677f\u57fa\u672c\u4e0a\u88ab\u5f7b\u5e95\u5c01\u95ed\u5f0f\uff0c\u8868\u5c42\u6bd4\u8f83\u6574\u5e73\u4f46\u6709\u805a\u919a\u5c42\u72b6\u53d1\u751f\uff0c\u76f8\u5339\u914d\u7684\u8868\u9762\u5f20\u529b\u4e3a106\u00b0\uff08\u56fe1b\uff09\u3002\u805a\u919a\u4e2d\u5939\u6742\u77f3\u58a8\u7a00\u540e\u7684\uff0c\u8bd5\u4ef6\u8868\u5c42\u88ab\u77f3\u58a8\u70ef\u7eb3\u7c73\u6280\u672f\u5c42\u72b6\uff081~3 \u03bcm\uff09\u5300\u79f0\u906e\u76d6\uff0c\u9540\u5c42\u4e2d\u77f3\u58a8\u70ef\u9010\u5c42\u7d2f\u52a0\uff08\u56fe1c\u548cd\uff09\u3002\u8fd9\u4e00\u7ed3\u679c\u663e\u793a\uff0c\u77f3\u58a8\u70ef\u5728\u805a\u919a\u4e2d\u5939\u6742\u6bd4\u8f83\u5300\u79f0\uff0c\u5fae\u5f27\u6c27\u5316\u5185\u5c42\u7684\u5b58\u6709\u4f7f\u8bd5\u4ef6\u8868\u5c42\u5177\u5907\u4e00\u5b9a\u7684\u8868\u9762\u7c97\u7cd9\u5ea6\uff0c\u52a0\u4e0a\u77f3\u58a8\u70ef\u7684\u7eb3\u7c73\u6280\u672f\u5c42\u72b6\u6784\u9020\u548c\u758f\u6c34\u6027\uff0c\u4f7fG\/SA\u590d\u5408\u888b\u5c42\u5177\u5907\u5fae\/\u7eb3\u7c73\u6280\u672f\u4e8c\u5143\u4e0d\u5149\u6ed1\u6784\u9020\uff0c\u8868\u9762\u5f20\u529b\u505a\u5230162\u00b0\u3002<\/p>\n<p style=\"margin-top: 0px; margin-bottom: 10px; text-align: center; line-height: 2em;\"><img decoding=\"async\" src=\"\/wp-content\/uploads\/2021\/12\/20211215133234-61b9ee724aee9.png\" \/><\/p>\n<p style=\"margin-top: 0px; margin-bottom: 10px; text-align: justify; line-height: 2em;\">2.2 \u9540\u5c42\u7684\u6709\u673a\u5316\u5b66\u6784\u6210<\/p>\n<p style=\"margin-top: 0px; margin-bottom: 10px; text-align: justify; line-height: 2em;\">\u56fe2\u63d0\u4f9b\u4e86SA\u5851\u6599\u8584\u819c\u548cG\/SA\u5851\u6599\u8584\u819c\u7684\u7ea2\u5916\u5149\u8c31\u56fe\u3002\u7531\u56fe2\u5f97\u77e5\uff0c\u7eafSA\u57281702 cm-1\u5904\u53d1\u751f\u4e86\u7fa7\u57fa\u7684C=O\u4f38\u7f29\u5f0f\u9707\u52a8\u5cf0\uff0c2849 cm-1\u548c2917 cm-1\u5904\u5404\u81ea\u53d1\u751f\u4e86\u7532\u57fa\u7684C\u2014H\u5bf9\u79f0\u6027\u548c\u4e0d\u5bf9\u79f0\u4f38\u7f29\u5f0f\u9707\u52a8\u5cf0\uff0c\u8fd9\u79cd\u5168\u662f\u805a\u919a\u7684\u7279\u70b9\u5cf0[19,20]\u3002\u6bd4\u7167\u7eafSA\u5851\u6599\u8584\u819c\u7684\u7ea2\u5916\u8c31\u56fe\u53d1\u89c9\uff0c\u5728G\/SA\u5851\u6599\u8584\u819c\u7684\u8c31\u56fe\u5185\u5305\u542b\u4e86SA\u7684\u7279\u70b9\u5cf0\uff0c\u5e76\u4e14\u57283466 cm-1\u548c1061 cm-1\u5904\u53d1\u751f\u7684\u5bbd\u800c\u5f3a\u7684\u5cf0\u3002\u8fd9\u5404\u81ea\u7531\u672a\u88ab\u5f7b\u5e95\u590d\u539f\u7684\u6c27\u5316\u77f3\u58a8\u70ef\u7684O\u2014H\u4f38\u7f29\u5f0f\u9707\u52a8\u548cC\u2014O \u4f38\u7f29\u5f0f\u9707\u52a8\u9020\u6210\u7684\uff0c\u8868\u660e\u77f3\u58a8\u70ef\u65e9\u5df2\u53d6\u5f97\u6210\u529f\u5730\u5939\u6742\u5230\u805a\u919a\u4e2d\u3002<\/p>\n<p style=\"margin-top: 0px; margin-bottom: 10px; text-align: center; line-height: 2em;\"><img decoding=\"async\" title=\"2.png\" src=\"\/wp-content\/uploads\/2021\/12\/20211215133234-61b9ee72bc005.png\" alt=\"2.png\" \/><\/p>\n<p style=\"margin-top: 0px; margin-bottom: 10px; text-align: justify; line-height: 2em;\">2.3 \u9540\u5c42\u7684\u8010\u8150\u8680\u6027\u80fd<\/p>\n<p style=\"margin-top: 0px; margin-bottom: 10px; text-align: justify; line-height: 2em;\">\u8d85\u758f\u6c34G\/SA\u590d\u5408\u888b\u5c42\u7684\u8010\u8150\u8680\u6027\u80fd\u6839\u636e\u52a8\u7535\u4f4d\u5dee\u7535\u6781\u6781\u5316\u3001\u5149\u7535\u50ac\u5316\u7279\u6027\u963b\u6297\u548c3.5 %NaCl\u9971\u548c\u6eb6\u6db2\u4e2d\u6ce1\u6d78\u8bd5\u9a8c\u7b49\u5149\u7535\u50ac\u5316\u65b9\u5f0f\u5f00\u5c55\u5256\u6790\u70b9\u8bc4\u3002<\/p>\n<p style=\"margin-top: 0px; margin-bottom: 10px; text-align: justify; line-height: 2em;\">\u56fe3\u5f97\u51fa\u4e86\u5404\u8bd5\u4ef6\u57283.5%NaCl\u9971\u548c\u6eb6\u6db2\u4e2d\u7684\u52a8\u7535\u4f4d\u5dee\u6781\u5316\u66f2\u7ebf\u3002\u5e94\u7528Tafel\u5916\u63a8\u6cd5\u83b7\u5f97\u5176\u6d78\u8680\u7535\u4f4d\u5dee\uff08Ecorr\uff09\u3001\u8150\u8680\u7535\u6d41\u76f8\u5bf9\u5bc6\u5ea6\uff08icorr\uff09\u548cTafel\u53c2\u91cf\uff08ba\u548cbc\uff09\u7b49\u5149\u7535\u50ac\u5316\u4e3b\u8981\u53c2\u6570\u3002\u7535\u6781\u6781\u5316\u7535\u963b\u5668\uff08Rp\uff09\u7531Stern-Geary\u516c\u5f0f\u8ba1\u7b97<\/p>\n<p style=\"margin-top: 0px; margin-bottom: 10px; text-align: center; line-height: 2em;\"><img decoding=\"async\" title=\"3.png\" src=\"\/wp-content\/uploads\/2021\/12\/20211215133234-61b9ee72dd5f0.png\" alt=\"3.png\" \/><\/p>\n<p style=\"margin-top: 0px; margin-bottom: 10px; text-align: justify; line-height: 2em;\">\u6c42\u53d6\u3002\u52a8\u7535\u4f4d\u5dee\u7535\u6781\u6781\u5316\u68c0\u6d4b\u7684\u5404\u5149\u7535\u50ac\u5316\u4e3b\u8981\u53c2\u6570\u5217\u4e8e\u88681\u3002\u4ece\u56fe3\u548c\u88681\u53ef\u4ee5\u770b\u5f97\u51fa\uff0c\u5bf9\u6bd4\u4e8eAZ91\u57fa\u6750\uff0c\u5fae\u5f27\u6c27\u5316\u819c\u5c42\u80fd\u4e0e\u6b64\u540c\u65f6\u6291\u6b62\u8d1f\u6781\u53cd\u6620\u548c\u9633\u6781\u6c27\u5316\u53cd\u6620\uff0c\u4f7fEcorr\u4ece-1.58 V\u6b63\u632a\u5230-1.49 V,icorr\u4ece7.87\u00d710-5 A\u964d\u81f31.59\u00d710-6 A\u3002G\/SA\u5851\u6599\u8584\u819c\u6d82\u6577\u4f7f\u590d\u5408\u578b\u540e\u819c\u5c42\u7684\u9633\u6781\u53cd\u6620\u548c\u9633\u6781\u6c27\u5316\u53cd\u6620\u83b7\u5f97\u8fdb\u4e00\u6b65\u7684\u6291\u6b62\uff0cEcorr\u6b63\u632a\u5230-1.18 V, icorr\u4f4e\u81f32.90\u00d710-9 A\u3002\u4e0e\u94dd\u9541\u5408\u91d1\u57fa\u6750\u5bf9\u6bd4\uff0c\u8d85\u758f\u6c34\u590d\u5408\u888b\u5c42\u7684icorr\u51cf\u5c11\u4e864\u4e2a\u91cf\u7ea7\uff0cRp\u63d0\u5347\u63d0\u5347\u4e865\u4e2a\u91cf\u7ea7\uff0c\u94dd\u9541\u5408\u91d1\u7684\u8010\u8150\u8680\u6027\u80fd\u83b7\u5f97\u4e86\u5f88\u5927\u7684\u63d0\u5347\u3002\u4e0e\u6b64\u540c\u65f6\uff0c\u8d85\u758f\u6c34\u590d\u5408\u888b\u5c42\u7684\u9633\u6781\u6c27\u5316\u6781\u5316\u66f2\u7ebf\u5728-1.1 V~-0.8 V\u7535\u4f4d\u5dee\u533a\u6bb5\u53d1\u751f\u5927\u533a\u57df\u7684\u949d\u5316\u533a\uff0c\u8868\u660e\u8d85\u758f\u6c34\u590d\u5408\u888b\u5c42\u5bf9\u94dd\u9541\u5408\u91d1\u7684\u4fdd\u62a4\u7279\u6027\u4f18\u826f\u3002\u505a\u4e3a\u8f83\u4e3a\u7684SA\u590d\u5408\u888b\u5c42\u6c92\u6709\u53d1\u751f\u949d\u5316\u4e2a\u4eba\u884c\u4e3a\uff0c\u4e14\u8010\u8150\u8680\u6027\u80fd\u6bd4\u4e0d\u4e0a\u8d85\u758f\u6c34\u590d\u5408\u888b\u5c42\u3002\u5176\u6839\u672c\u539f\u56e0\u662f\uff0c\u77f3\u58a8\u70ef\u7684\u6dfb\u52a0\u4f7f\u8bd5\u4ef6\u8868\u5c42\u8d85\u758f\u6c34\u5408\u7406\u5730\u964d\u4f4e\u4e0e\u8150\u8680\u6027\u7269\u8d28\u7684\u89e6\u78b0\u603b\u9762\u79ef\uff0c\u5e76\u4e14\u77f3\u58a8\u70ef\u5728\u5851\u6599\u8584\u819c\u4e2d\u9010\u5c42\u7d2f\u52a0\u4f7f\u5851\u6599\u8584\u819c\u7684\u673a\u68b0\u9694\u7edd\u7279\u6027\u66f4\u5f3a\u3002<\/p>\n<p style=\"margin-top: 0px; margin-bottom: 10px; text-align: center; line-height: 2em;\"><img decoding=\"async\" title=\"4.png\" src=\"\/wp-content\/uploads\/2021\/12\/20211215133234-61b9ee72f0dfc.png\" alt=\"4.png\" \/><\/p>\n<p style=\"margin-top: 0px; margin-bottom: 10px; text-align: justify; line-height: 2em;\">\u4f9d\u636e\u5149\u7535\u50ac\u5316\u7279\u6027\u963b\u6297\u8fdb\u4e00\u6b65\u79d1\u5b66\u7814\u7a76\u4e86\u5404\u8bd5\u4ef6\u7684\u6d78\u8680\u4e2a\u4eba\u884c\u4e3a\u3002\u56fe4\u5f97\u51fa\u4e86\u5404\u8bd5\u4ef6\u57283.5%NaCl\u9971\u548c\u6eb6\u6db2\u4e2d\u5f97\u5230\u7684\u5149\u7535\u50ac\u5316\u7279\u6027\u963b\u6297Nyquist\u56fe\uff0c\u56fe5\u5f97\u51fa\u4e86\u76f8\u5339\u914d\u7684\u7b49\u6548\u7535\u8def\u56fe\u3002\u4ece\u56fe4\u53ef\u4ee5\u770b\u5f97\u51fa\uff0c\u4e0d\u4e00\u6837\u89e3\u51b3\u7684AZ91\u94dd\u9541\u5408\u91d1\u4e3b\u8981\u8868\u73b0\u51fa\u4e0d\u4e00\u6837\u7684\u7279\u6027\u963b\u6297\u4e2a\u4eba\u884c\u4e3a\u3002\u57fa\u6750\u94dd\u9541\u5408\u91d1\u7684\u7279\u6027\u963b\u6297\u56fe\u7531\u4e00\u4e2a\u4e2d\u9ad8\u9891\u7387\u533a\u7684\u5bb9\u6297\u5f27\u548c\u4e00\u4e2a\u4f4e\u9891\u7387\u533a\u7684\u611f\u6297\u5f27\u6784\u6210\uff0c\u5728\u5176\u4e2d\u5bb9\u6297\u5f27\u662f\u8f90\u5c04\u8dc3\u8fc1\u5168\u8fc7\u7a0b\u4ea7\u751f\u7684\uff0c\u800c\u611f\u6297\u5f27\u4e0e\u9541\u7684\u878d\u89e3\u76f8\u5173\uff0c\u76f8\u5339\u914d\u7740\u70b9\u8680\u7684\u53d1\u751f\uff0c\u5176\u95ed\u5408\u7535\u8def\u5982\u4e0b\u56fe5a\u6240\u663e\u793a\uff0cRs\u4e3a\u9971\u548c\u6eb6\u6db2\u7535\u963b\u5668\uff0cCPEdl\u4e3a\u53cc\u7535\u5c42\u7535\u5bb9\u5668\uff0cRct\u4e3a\u8f90\u5c04\u8dc3\u8fc1\u7535\u963b\u5668\uff0cRsf\u4e3a\u6d78\u8680\u7269\u8d28\u7535\u963b\u5668\uff0cL\u4e3a\u611f\u6297\u3002\u5fae\u5f27\u6c27\u5316\u540e\u94dd\u9541\u5408\u91d1\u7684\u7279\u6027\u963b\u6297\u56fe\u548c\u57fa\u6750\u7684\u7c7b\u4f3c\uff0c\u5176\u7b49\u6548\u7535\u8def\u56fe\u4e5f\u7c7b\u4f3c\uff08\u56fe5b\uff09\uff0c\u63d0\u5347\u4e86\u9540\u5c42\u7535\u963b\u5668Rcoat\u548c\u9540\u5c42\u7535\u5bb9\u5668CPEcoat\u3002\u5fae\u5f27\u6c27\u5316\u540e\u5bb9\u6297\u5f27\u76f4\u5f91\u589e\u52a0\uff0c\u76f8\u5339\u914d\u7740\u8f90\u5c04\u8dc3\u8fc1\u7535\u963b\u5668\u4ece6.68\u00d7102 \u03a9cm2\u63d0\u5347\u52304.04\u00d7104 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2em;\">G\/SA\u590d\u5408\u888b\u5c42\u5bf9AZ91\u94dd\u9541\u5408\u91d1\u7684\u51fa\u8272\u9632\u8150\u8680\u7279\u6027\uff0c\u5176\u5177\u4f53\u7f18\u6545\u4e3a\uff1a\u6700\u5148\uff0cMAO\u819c\u5c42\u505a\u4e3a\u5185\u5c42\uff0c\u662f\u4e00\u79cd\u5728\u57fa\u6750\u8868\u5c42\u539f\u70b9\u751f\u957f\u53d1\u80b2\u7684\u7edd\u7f18\u9676\u74f7\u5c42\uff0c\u4e0e\u57fa\u6750\u878d\u5408\u5bc6\u5207\uff0c\u4e14\u672c\u8eab\u7684\u7535\u7edd\u7f18\u6027\u80fd\u597d\uff0c\u5728\u6d78\u8680\u63a7\u5236\u56de\u8def\u4e2d\u5e72\u9884\u9ad8\u7535\u963b\u5668\uff0c\u8fdb\u800c\u6291\u6b62\u4e86\u57fa\u6750\u6d78\u8680\u3002\u6b21\u4e4b\uff0cG\/SA\u5851\u6599\u8584\u819c\u505a\u4e3a\u8868\u9762\u5bc6\u5c01\u6027\u4e86\u5fae\u5f27\u6c27\u5316\u7684\u5fae\u5b54\u677f\u548c\u7f1d\u9699\uff0c\u5408\u7406\u5730\u6291\u6b62\u4e86\u70b9\u8680\u7684\u4ea7\u751f\uff0c\u5e76\u4e14\u5177\u5907\u758f\u6c34\u6027\u548c\u4e0d\u900f\u6c34\u6027\u7684\u77f3\u58a8\u70ef\u5c42\u72b6\u5728\u5851\u6599\u8584\u819c\u4e2d\u9010\u5c42\u7d2f\u52a0\u4ea7\u751f\u4e00\u5c42\u7269\u7406\u5b66\u963b\u7edd\u5c42\uff0c\u4f7f\u6d78\u8680\u7269\u8d28\u96be\u4ee5\u6839\u636e\uff0c\u4f7f\u590d\u5408\u888b\u5c42\u7684\u9632\u9508\u7279\u6027\u8fdb\u4e00\u6b65\u63d0\u9ad8\u3002\u6700\u7ec8\uff0c\u4f9d\u636eCassie\u65b9\u7a0b\u5f0f<\/p>\n<p style=\"margin-top: 0px; margin-bottom: 10px; text-align: center; line-height: 2em;\"><img decoding=\"async\" title=\"7.png\" src=\"\/wp-content\/uploads\/2021\/12\/20211215133235-61b9ee739a815.png\" alt=\"7.png\" \/><\/p>\n<p style=\"margin-top: 0px; margin-bottom: 10px; text-align: justify; line-height: 2em;\">f=cos\u03b8* 1cos\u03b8c 1f=cos\u03b8* 1cos\u03b8c 1\u5236\u53d6\u7684G\/SA\u590d\u5408\u888b\u5c42\u8d85\u758f\u6c34\u3002\u5728\u5176\u4e2d\uff0c ff \u4e3a\u975e\u5747\u76f8\u89e6\u78b0\u603b\u9762\u79ef\u767e\u5206\u6bd4\uff0c \u03b8*\u03b8* \u4e3a\u8868\u89c2\u8868\u9762\u5f20\u529b\uff0c \u03b8c\u03b8c 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